报告地点：理化楼C401
报告人：吴小锋
主办单位：化学化工学院
报告人简介：
吴小锋，男，博士，首席研究员，博士生导师。2007年毕业于浙江理工大学，获理学学士学位；2009年毕业于法国雷恩第一大学，获硕士学位；2012年毕业于德国罗斯托克大学-莱布尼兹催化研究所，获得自然科学博士学位。毕业后留所开展独立研究，2017年完成法国雷恩第一大学的Habilitation，获得教授资格。2020年加入大连化物所，聘为首席研究员，张大煜优秀学者。2013年获得浙江省"钱江学者"特聘教授，浙江省151人才第一层次，2015年获得Wiley优秀作者奖，2016年浙江省杰出青年基金和第16届国际催化会议青年化学家奖，2017年Thieme Chemistry Journal Award，2019年入选中国科学院百人计划A，2021年入选国家高层次人才引进计划-长期项目。在Angew. Chem. Int. Ed., JACS 等国际高档次杂志上发表SCI学术论文550多篇，专著10部，专利20多项。
报告简介：
Transition-metal-catalyzed carbonylations are one of the most fundamental and ideal reactions for the synthesis of numerous value-added carbonyl-containing compounds from readily available starting materials. However, most of the developed carbonylation procedures are based on expensive Noble metal catalysts. The exploration of cheap metals in carbonylation chemistry is attractive. On the other hand, copper is known as an environmental benign metal catalyst with non-expensive and abundant characters which has been extensively explored and applied in various organic transformations. Its outstanding catalytic activities in cross-coupling chemistry (with bond formation including C-N, C-O, etc.) are even better than noble metal catalysts such as palladium. Its powerful catalytic ability can also be proven by the known named reactions based on copper catalysts, for example the Chan-Lam reaction, Ullman coupling, Glaser reaction, and so on. However, the application of copper catalyst in carbonylative transformations has been less reported. Here, our recent results on copper-catalyzed carbonylation reactions will be presented. Staring from alkanes, alkenes, alkynes, and alkyl halides, various carbonylated products can be effectively produced.
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